Biocrude Production via Non-Catalytic Supercritical Hydrothermal Liquefaction of Fucus vesiculosus Seaweed Processing Residues
نویسندگان
چکیده
The potential of using cold water brown macroalgae Fucus vesiculosus for biocrude production via non-catalytic supercritical hydrothermal liquefaction (HTL) was studied. Demineralization, residue neutralization, and high value-added product (alginate fucoidan) extraction processes were carried out before the biomass HTL production. Acid leaching three demineralization agents: distilled water, dilute citric acid solution, diluted acidic aqueous by-product from a continuous pilot facility. Alginate extracted H2SO4 NaCO3 bathing, fucoidan CaCl2. Experimental data show that none agents greatly efficient in removing inorganics, with extensive neutralization reaching highest ash removal efficiency 47%. produced 6 sets biocrudes characterized by elemental thermogravimetric analyses. Short (10-min retention) extent also investigated. Highest yields recorded when liquefying non-neutralized leaching, alginate, residues. On other hand, thermochemical conversions short retention time HTL, full extent, baseline (dried raw macroalgae) performed worse. Specifically, yield 28.2 ± 2.5 wt.% on dry ash-free feedstock basis alginate Moreover, energy recovery 52.8% converting
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ژورنال
عنوان ژورنال: Recycling
سال: 2021
ISSN: ['2313-4321']
DOI: https://doi.org/10.3390/recycling6030045